PECULIARITIES OF DISTRIBUTION AND COMPOSITION OF BETAFITE FROM DIFFERENT FORMATIONS OF THE ALDAN SHIELD (SAKHA-YAKUTIA)

Authors

  • V. Guliy Ivan Franko National University of Lviv, Geology Faculty, 4 Hrushevsky Str., Lviv, 79005, Ukraine
  • І. Poberezhska Ivan Franko National University of Lviv, Geology Faculty, 4 Hrushevsky Str., Lviv, 79005, Ukraine

DOI:

https://doi.org/10.17721/1728-2713.84.01

Keywords:

betafite, titanite, Nb and Ta, metamorphic apatite-carbonate ores, Aldan Shield, pegmatites, metasomatites, skarns, carbonatites, C–O isotopes

Abstract

Character of Nb and Ta distribution in the different geological formations of the Aldan Shield are given in this article. To get idea about betafite from different endogenic etalon formations the authors analyzed its well known locations in the pegmatites, skarns, carbonatites, metasomatites and late veins segregations. Geological setting and mineralogical composition of the apatite-bearing rocks from the Aldan Shield are described, and the most significant in scale metamorphosed carbonate and silicate varieties among them have been distinguished. Apatite mineralization in magnesium skarns and metasomatites is developed locally. Titanite and betafite are the main concentrators of Nb and Ta and apatite is typical accompanying mineral in the studied rocks. Betafite was detected in the pegmatite bodies from magnesium skarns and metasomatites of the Shield with irregular distribution within rocks rich and poor in apatite, but was not found in the most developed apatite-carbonate rocks which are regarded as ores of the Seligdar type, so it cannot be mineralogical indicator for this type of ores. Late carbonate generations are significantly enriched in light carbon and oxygen isotopes in contrast to positive δ13С values in apatitecarbonate bodies of the Seligdar deposit and its family and the highest δ18О values. We used these indicators to distinguish origin of the rocks with various carbonate generations, which have different amounts of betafite. Appearance of betafite is determined by primary composition of the initial rocks. Chemical composition of betafites from the skarns and metasomatites is similar, but with local variations. The most significant feature of the mineral composition is very low Ta content. Titanite is characterized by variable amounts of Nb and Ta in scale of sectors as well as within separate grains.  

References

Bjorlykke, H. (1937). Mineral parageneses of some granite pegmatites near Kragero, southern Norway. Norsk Geol. Tidsskr., 17, 1-16.

Bulakh, A.G., Guliy, V.N., Zolotarev, A.A. (1990). Phosphorus Ores in Precambrian Rocks of the Aldan Shield, Leningrad: Publishing House of Leningrad University. [in Russian]

Camara, F., Williams, C.T., Della Ventura, G., Oberti, R., Caprilli, E. (2004). Non-metamict betafite from Le Carcarelle (Vico volcanic complex, Italy): occurrence and crystal structure. Mineralogical Magazine, 68 (6), 939-950.

Chen, Y.-X., Zheng, Y.-F. (2015). Extreme Nb/Ta fractionation in metamorphic titanite from ultrahigh-pressure metagranite. Geochimica et Cosmochimica Acta, 150, 53-73.

Christy, A.G., Atencio, D. (2013). Clarification of status of species in the pyrochlore supergroup. Mineralogical Magazine, 77, 13-20.

Entin, A.R., Kravchenko, S.M., Tian, O.A., Makhotko, V.F. (1987). Betafiteapatite association as a formation indicator of the Seligdar type ores. Reports of USSR AN, 293(4), 948-951. [in Russian]

Entin, A.R., Tian, O.A., Makhotko, V.F., Kravchenko, S.M. (1989). Titanoniobates in the Seligdar type ores. Soviet Geology, 2, 83-90. [in Russian]

Goroshko, M.V., Osypov, A.L., Kirilov, V.E., Solomatin, G. B. (1995). Possibilities of discovery of new kinds of deposits at the Southern-Eastern part of the Aldan Shield. Pacific Ocean Geology, 2, 111-118. [in Russian]

Guliy, V., Furuta, T., Bilyk, N. (2017). Features of REE and Sr distribution in apatite of different genesis from the Aldan Shield (Siberian Platform). Mineralogical Review, 67(2), 3–14.

Guliy, V.N., Wada, H. (2003). Macro- and Micro-variations in the Carbon and Oxygen Isotopic Composition of Precambrian Carbonates from the Aldan Shield. Geochemistry International, 41(5), 431-439.

Guliy, V.N., Wada, H. (2004). Carbon and Oxygen Isotopic Compositions of Carbonates from Precambrian Apatite-Bearing Carbonate Rocks of the Aldan Shield. Lithology and Mineral Resources, 39(3), 243-353.

Hogarth, D.D. (1959). A mineralogical study of pyrochlore and betafite. PhD Thesis. Montreal, McGiIl University.

Hogarth, D.D. (1977). Classification and nomenclature of the pyrochlore group. American Mineralogist, 62, 403-410.

Kapustin, Yu. L. (1971). Mineralogy of carbonatites. Moscow: Nauka. [in Russian]

Kitsul, V.I., Bogomolova, L.M., Duk, V.L. (1979). Reflection of the Tectonic Structure of the Aldan Shield in Metamorphic and Mineral Facies Metamorphism of Rocks in the Urals. Sverdlovsk, 41-46. [in Russian]

Lents, D., Suzuki, K. (2001). A low F pegmatite-related Mo skarn from the southwestern Grenville Province, Ontario, Canada: phase equilibria and petrogenetic implication. Economic Geology, 95(6), 1319–1337

Lumpkin, G.R., Ewing, R.C., Williams, C.T., Mariano, A.N. (2001). An overview of the crystal chemistry, durability, and radiation damage effects of pyrochlore from natural systems/ Scientific Basis for Nuclear Waste Management XXIV. Pennsylvania: Warrendale Publishers, 663, 921-934.

Mineev, D.А., Ilina, О. N., Kravchenko, S.М., et al. (1978). About geochemical features of apatite mineralization of the Seligdar type. EI. VIEMS, Geol., methods of exploration and estimate. Non-ore deposits, 3, 8-17. [in Russian]

Minerals (1967). Moscow. Nauka, 2(3). [in Russian]

Minerals (1968). Moscow. Nauka, 3(2). [in Russian]

Pieczka, A. (2010). Primary Nb-Ta minerals in the Szklary pegmatite, Poland: New insights into controls of crystal chemistry and crystallization sequences. American Mineralogist, 95(10), 1478-1492.

Pršek, J., Majka, J., Uher, P., Chudík, P. (2010). Niobium-tantalum minerals in the Skoddefjellet NYF granitic pegmatite, Svalbard Archipelago,Norway: Primary versus secondary assemblage. Neues Jahrbuch für Mineralogie Abhandlungen, 187(3), 235–248.

Pushkarev, Yu.D., Guliy, V.N., Kravchenko, M.P., Ryungenen, G.I. (1989). The Pb and Sr Isotopic compositions of apatite-silicate and carbonate-apatite ore deposits of the Aldan Shield. XII All-Union Symposium on Stable Isotopic Geohemistry, Moscow, 10-11. [in Russian]

Radkov, A.V., Molchanov, A.V., Artemev, D.S. et al. (2015). State Geological Map of Russian Federation. Scale 1: 1000 000 (third generation). AldanZabaikale Serie, 0-51 – Aldan list. Explanatory note, St.Petersburg: VSEGEI. [in Russian]

Sakharova, M.S. (1955). Metamorphised apatite-bearing Archean rocks of the Southern Near Baikal. Moscow: Processing of SIChM, 70-94. [in Russian]

Turner, H.W. (1928). Review of the Radioactive Minerals of Madagascar. Economic Geology, 23, 62-84.

Vinogradov, V.I., Egin, V.I., Kichigin, L.I. et al. (1975). Role of the Lithologic Control of Apatite Mineralization in Archean Rocks of the Aldan Shield (Evidence from Sulfur Isotopic Composition). Litology i Poleznye Iskopaemye, 5, 117-127. [in Russian].

Downloads

Published

2025-01-16

How to Cite

Guliy, V., & Poberezhska І. (2025). PECULIARITIES OF DISTRIBUTION AND COMPOSITION OF BETAFITE FROM DIFFERENT FORMATIONS OF THE ALDAN SHIELD (SAKHA-YAKUTIA). Visnyk of Taras Shevchenko National University of Kyiv. Geology, 1(84), 8-15. https://doi.org/10.17721/1728-2713.84.01